Iron mixed-valence complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto =C2O2S2), shows a spin-entropy driven phase transition called charge transferphase transition around 120K and a ferromagnetic transition at 6.5 K. These phase transitions remarkably depend on the hexagonal ring size intwo-dimensional honeycomb network structure of [FeIIFeIII(dto)3]∞. In order to control the magnetic properties and the electronic state in thedto-bridged iron mixed-valence system by means of photo-irradiation, we have synthesized a photo-sensitive organic–inorganic hybrid system,(SP)[FeIIFeIII(dto)3] (SP = spiropyran), and investigated the photo-induced effect on the magnetic properties by the measurements of magneticsusceptibility, ESR, IR, UV–vis and 57FeM

• 本站资源为会员上传分享交流与学习,如有侵犯您的权益,请联系我们删除.
• 建筑资料网是交换下载平台，提供交流渠道，下载内容来自于网络，除下载问题外，其它问题请自行百度。
• 本站已设置防盗链，请勿用迅雷、QQ旋风等多线程下载软件下载资源，下载后用WinRAR最新版进行解压.
• 如果您发现内容无法下载，请稍后再次尝试；或者到消费记录里找到下载记录反馈给我们.
• 下载后发现下载的内容跟说明不相乎，请到消费记录里找到下载记录反馈给我们，经确认后退回积分.
• 分卷压缩的大文件,请按顺序改名为:1.rar,2.rar,3.rar...再进行解压
• 如下载前有疑问，可以通过点击"提供者"的名字，查看对方的联系方式，联系对方咨询.